The 88th Annual Academy Awards signify the most prestigious night in Hollywood —and not to mention the most serious, high-stakes red carpet night of the year. See who made the biggest statements, and won our award for best-dressed even before the ceremony began.

Best Actress nominee Brie Larson looks like a winner in Gucci.

Best Supporting Actress nominee Alicia Vikander described her Louis Vuitton dress as “dusty yellow” during the pre show.

YASS Queen! All hail Cate Blanchett, in seafoam Armani Privé.

Best Actress nominee Saoirse Ronan in Calvin Klein Collection.

RELATED: The worst dressed at the Oscars 2016

And the gold statue for most sizzling look goes to Margot Robbie in Tom Ford.

By now. Rooney Mara knows how to work a white Givenchy Haute Couture dress, her go to for award shows.

Well hello, orange! Olivia Munn in Stella McCartney.

Lada Gaga channeling a modern day Marilyn Monroe in this Brandon Maxwell jumpsuit gown.

Sofia Vergara, in Marchesa, said her pulled-back ’do was new look for her.

Jacob Tremblay continues to be adorable. Tonight he’s in Armani.

Plunging neckline, Neil Lane choker, braided up ‘do —Yes to it all. Olivia Wilde in Valentino Haute Couture.